Reaction uses carbon dioxide to make carbon-based semiconductor

A materials scientist at Michigan Technological University has discovered a chemical reaction that not only eats up the greenhouse gas carbon dioxide, it also creates something useful. And, by the way, it releases energy.

Making carbon-based products from carbon dioxide is nothing new, but carbon dioxide molecules are so stable that those reactions usually take up a lot of energy. If that energy were to come from fossil fuels, over time the chemical reactions would ultimately result in more carbon dioxide entering the atmosphere—defeating the purpose of a process that could otherwise help mitigate climate change.

Professor Yun Hang Hu’s research team developed a heat-releasing reaction between carbon dioxide and Li3N that forms two chemicals: amorphous carbon nitride, a semiconductor; and lithium cyanamide, a precursor to fertilizers.

“The reaction converts carbon dioxide to a solid material,” said Hu. “That would be good even if it weren’t useful, but it is.”

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