Category Archives: LED Manufacturing

Lumileds today announced the appointment of Dr. Jonathan Rich as Chief Executive Officer. Dr. Rich most recently served as Chairman and CEO of Berry Global, Inc., a Fortune 500 specialty materials and consumer packaging company, from 2010 to 2018. Dr. Rich succeeds Mark Adams, who is stepping down as CEO and from the board of directors but will remain in an advisory role to the company.

“I am very pleased to be joining Lumileds and am looking forward to building on the company’s differentiated lighting technology foundation to increase the value we can deliver to customers across a broad set of industries,” said Dr. Rich. “The opportunity for lighting innovation to make a positive impact on safety and sustainability is tremendous.”

Before Dr. Rich held the position of Chairman and CEO of Berry Global, he was president and CEO at Momentive, a specialty chemical company headquartered in Albany, New York. Prior to that, he held positions with Goodyear Tire & Rubber Company, first as President of the Global Chemicals business and subsequently as President of Goodyear’s North American Tire Division. Dr. Rich spent his formative years at General Electric, first as a research scientist at GE Global Research and then in a series of management positions with GE Plastics. He received a Bachelor of Science degree in chemistry from Iowa State University and a Ph.D. in chemistry from the University of Wisconsin-Madison. He has been a visiting lecturer at Cornell University Johnson School of Business since 2017.

“Mark Adams has made significant contributions to Lumileds during his tenure, leading the transition to an independent company and cultivating a culture of innovation and customer focus,” said Rob Seminara, a senior partner at Apollo and chairman of the board of Lumileds. “On behalf of the Board of Directors of Lumileds, we would like to thank him for his service to the company and wish him the very best in his future endeavors. We are very excited Jon will be joining Lumileds to drive the next phase of innovation and growth and we look forward to working with him again.”

Added Adams: “It has been a great experience leading Lumileds’ transition to an independent company that is focused on delivering lighting solutions that truly make a positive impact in the world. I would like to thank the employees of Lumileds and the Apollo team for their support and wish the company much success in the future.”

Metal halide perovskites are regarded as next generation materials for light emitting devices (LEDs). A recent joint-research co-led by the scientist from City University of Hong Kong (CityU) has developed a new and efficient fabrication approach to produce all-inorganic perovskite films with better optical properties and stability, enabling the development of high colour-purity and low-cost perovskite LEDs with a high operational lifetime.

a) Device structure and a corresponding cross-sectional TEM image of the multi-layer PeLEDs; b) Schematic flat-band energy diagram of the PeLED; c) Normalized photoluminescence spectrum of the CsPbBr3 film, and electroluminescence spectrum of the PeLED at an applied voltage of 5.5 V Credit: City University of Hong Kong

Perovskite LEDs (PeLEDs) are an emerging light-emitting technology with advantages of low manufacturing cost, high light quality and energy efficiency. Metal halide (meaning compounds of metals with chlorine, bromine or iodine) perovskites have recently attracted a lot of attention as promising materials for solution-processed LEDs, owing to their excellent optical properties, such as saturated emission colors and easy color tunability.

In particular, perovskites based on inorganic cesium cations, namely CsPbX3 (where X can be chlorine, bromine and iodine), exhibit better thermal and chemical stability compared to the organic-inorganic ‘hybrid’ metal halide perovskites, and may thus provide the base for high-performance LEDs with reasonable operational stability. But the previous inorganic PeLEDs exhibited relatively poor electro-luminescence performance due to their large perovskite grain sizes.

Now a team of researchers at CityU and at Shanghai University in mainland China has developed an efficient fabrication approach to make smooth inorganic perovskite films with substantially enhanced performance and stability. Their findings appear in the latest issue (2019, 10, 665) of the scientific journal Nature Communications, titled “Trifluoroacetate induced small-grained CsPbBr3 perovskite films result in efficient and stable light-emitting devices “.

The team has found that using cesium trifluoroacetate (TFA) as the cesium source in the one-step solution coating, instead of the commonly used cesium bromide (CsBr), enables fast crystallization of small-grained CsPbBr3 perovskite crystals, forming the smooth and pinhole-free perovskite films. This is because the interaction of TFA- anions with Pb2+ cations in the CsPbX3 precursor solution greatly improves the crystallization rate of perovskite films and suppresses surface defects.

As a result, the team has managed to make efficient and stable green PeLEDs based on these films, with a maximum current efficient of 32.0 cd A-1 corresponding to an external quantum efficiency of 10.5% – a level generally considered as satisfactory in existing PeLEDs.

More importantly, the all-inorganic perovskite LEDs based on these films demonstrated a record operational lifetime. They have a half-lifetime of over 250 hours at an initial luminance of 100 cd m-2, which is a 17 times improvement in operational lifetime compared with CsBr-derived PeLED.

“Our study suggests that the high color-purity and low-cost all-inorganic lead halide perovskite films can be developed into highly efficient and stable LEDs via a simple optimization of the grain boundaries,” says Andrey Rogach, Chair Professor of Photonics Materials at CityU, who is one of the correspondence authors of the paper.

“I foresee significant application potential of such films, as they are easy to fabricate and can be easily deposited by printing to realise various optoelectronic devices,” he adds.

Another correspondence author of the paper is Professor Yang Xuyong from Shanghai University. The first authors are Wang Haoran at Shanghai University and Zhang Xiaoyu, a former visiting research student at CityU, now working as a postdoc at Jilin University.

Robust demand for more content for mobile, Internet of Things (IoT), automotive and industrial applications will drive production of 700,000 200mm wafers from 2019 to 2022, a 14 percent increase, reports SEMI, the global industry association serving the electronics manufacturing supply chain, in its latest Global 200mm Fab Outlook. The increase brings total 200mm wafer fab capacity to 6.5 million wafers per month as many devices have found their sweet spot with 200mm wafer fabrication.

Strong 200mm wafer growth mirrors sound capacity demand seen across various industry segments. From 2019 to 2022, for example, wafer shipments for MEMS and sensors devices are expected to increase 25 percent while shipments for power devices and foundries are forecast to jump 23 percent and 18 percent, respectively, the SEMI Global 200mm Fab Outlook shows. The increases in 200mm fab count and installed capacity reflect continuing 200mm industry strength as it continues to add capacity and even open new fabs.

The SEMI Global 200mm Fab Outlook report has added seven new facilities, with 160 updates to 109 fabs, since its most recent publication in July 2018. A total of 16 new facilities or lines, 14 of them volume fabs, are expected to begin operation between 2019 and 2022. The report takes into account both equipment transferred from one fab to another and equipment revitalized after being held in storage, such as for SK Hynix and Samsung.

Across the industry, recent sudden changes in investment plans for leading-edge devices such as memory have triggered a projected double-digit decline in spending in 2019. However, with demand for mature devices using wafers 200mm and smaller stable or evening growing, it would be no surprise to see plans emerge for even more 200mm capacity and new fabs to meet growing demand.

More information about the SEMI Global 200mm Fab Outlook report from 2019 to 2022 is available here.

Leti, an institute of CEA-Tech, has developed a novel retinal-projection concept for augmented reality (AR) uses based on a combination of integrated optics and holography. The lens-free optical system uses disruptive technologies to overcome the limitations of existing AR glasses, such as limited field-of-view and bulky optical systems.

TVs and smartphones that project digital images emit light all around them, as quasi-isotropic sources. Because the images are projected generally over the air without directivity, many viewers see the same image. In typical AR glasses, images are transmitted close to the eyes (high directivity) by a microdisplay that includes an optical system and an optical combiner.

These microdisplays create a small near-to-eye image, which is transformed by the optical system, enabling the user to see it despite the short focusing distance. The combiner superimposes the digital image to the viewers’ vision of the real environment.

CEA-Leti’s innovation is a transparent retinal-projection device that projects various light waves to the eyes from a glass surface. Images are formed in the retina by the interference of light waves, which eliminates the need for optical systems or combiners. The light propagating in the air doesn’t form an image until it interferes precisely in the retina.

CEA-Leti presented its results Feb. 6 at SPIE Photonics West 2019 in a paper titled “Integrated Optical Network Design for a Retinal Projection Concept Based on Single-Mode Si3N4 Waveguides at 532 nm”.

The project focused on the design and numerical simulations of integrated Si3N4 optical components and the optical circuit at λ = 532 nm. It required building blocks for designing an optical integrated circuit capable of creating an array of emissive points. Starting with single-mode waveguides to efficiently transport light around the circuit, many other components were designed to manipulate light in different locations. Components for extracting the light, such as diffraction gratings, were also designed and simulated. The team minimized losses of different parts of the circuit, such as waveguide-bending areas, to increase energy efficiency of the system.

CEA-Leti’s integration of the device and its use of a holographic layer also allow creation of compact AR glasses with a larger field-of-view than existing systems, while the transparent retinal projection device allows ambient light to pass through the device for enhanced AR applications.

“Combining integrated optics and holography is a new research area for the scientific community developing display applications,” said Basile Meynard, a Ph.D. student and lead author of the paper. “It is also a way to imagine a display device that works more as a data transfer system than as an imaging system.”

The novel approach will require further development before it reaches the commercialization stage. In the medium to long term, the retinal projection concept is expected to support more compact and higher virtual-image quality applications similar to existing AR glasses.

This research project builds on CEA-Leti’s many years of development of micro-displays for near-to-eye displays, such as organic LED technologies (OLED) and liquid crystal devices (LCD). More recently, the institute has made significant strides in the field of inorganic LED display manufacturing.

“Our teams are continuously looking for potential disruptive technologies that could pave the way to new families of display devices down the road,” said Christophe Martinez, optical senior scientist and project leader in Leti. “The investigation on retinal displays is part of this exploration of future optical solutions.”

Nanolasers have recently emerged as a new class of light sources that have a size of only a few millionths of a meter and unique properties remarkably different from those of macroscopic lasers. However, it is almost impossible to determine at what current the output radiation of the nanolaser becomes coherent, while for practical applications, it is important to distinguish between the two regimes of the nanolaser: the true lasing action with a coherent output at high currents and the LED-like regime with incoherent output at low currents. Researchers from the Moscow Institute of Physics and Technology developed a method that allows to find under what circumstances nanolasers qualify as true lasers. The research was published in Optics Express.

Nanolaser test. Credit: @tsarcyanide/MIPT Press Office

Lasers are widely used in household appliances, medicine, industry, telecommunications, and more. Several years ago, lasers of a new kind were created, called nanolasers. Their design is similar to that of the conventional semiconductor lasers based on heterostructures, which have been known for several decades. The difference is that the cavities of nanolasers are exceedingly small, on the order of the wavelength of the light emitted by these light sources. Since they mostly generate visible and infrared light, the size is on the order of one millionth of a meter.

In the near future, nanolasers will be incorporated into integrated optical circuits, where they are required for the new generation of high-speed interconnects based on photonic waveguides, which would boost the performance of CPUs and GPUs by several orders of magnitude. In a similar way, the advent of fiber optic internet has enhanced connection speeds, while also boosting energy efficiency.

And this is by far not the only possible application of nanolasers. Researchers are already developing chemical and biological sensors, mere millionths of a meter large, and mechanical stress sensors as tiny as several billionths of a meter. Nanolasers are also expected to be used for controlling neuron activity in living organisms, including humans.

For a radiation source to qualify as a laser, it needs to fulfill a number of requirements, the main one being that it has to emit coherent radiation. One of the distinctive properties of a laser, which is closely associated with coherence, is the presence of a so-called lasing threshold. At pump currents below this threshold value, the output radiation is mostly spontaneous and it is no different in its properties from the output of conventional light emitting diodes (LEDs). But once the threshold current is reached, the radiation becomes coherent. At this point the emission spectrum of a conventional macroscopic laser narrows down and its output power spikes. The latter property provides for an easy way to determine the lasing threshold — namely, by investigating how output power varies with pump current (figure 1A).

Many nanolasers behave the way their conventional macroscopic counterparts do, that is, they exhibit a threshold current. However, for some devices, a lasing threshold cannot be pinpointed by analyzing the output power versus pump current curve, since it has no special features and is just a straight line on the log-log scale (red line in figure 1B). Such nanolasers are known as “thresholdless.” This begs the question: At what current does their radiation become coherent, or laserlike?

The obvious way to answer this is by measuring the coherence. However, unlike the emission spectrum and output power, coherence is very hard to measure in the case of nanolasers, since this requires equipment capable of registering intensity fluctuations at trillionths of a second, which is the timescale on which the internal processes in a nanolaser occur.

Andrey Vyshnevyy and Dmitry Fedyanin from the Moscow Institute of Physics and Technology have found a way to bypass the technically challenging direct coherence measurements. They developed a method that uses the main laser parameters to quantify the coherence of nanolaser radiation. The researchers claim that their technique allows to determine the threshold current for any nanolaser (figure 1B). They found that even a “thresholdless” nanolaser does in fact have a distinct threshold current separating the LED and lasing regimes. The emitted radiation is incoherent below this threshold current and coherent above it.

Surprisingly, the threshold current of a nanolaser turned out to be not related in any way to the features of the output characteristic or the narrowing of the emission spectrum, which are telltale signs of the lasing threshold in macroscopic lasers. Figure 1B clearly shows that even if a well-pronounced kink is seen in the output characteristic, the transition to the lasing regime occurs at higher currents. This is what laser scientists could not expect from nanolasers.

“Our calculations show that in most papers on nanolasers, the lasing regime was not achieved. Despite researches performing measurements above the kink in the output characteristic, the nanolaser emission was incoherent, since the actual lasing threshold was orders of magnitude above the kink value,” Dmitry Fedyanin says. “Very often, it was simply impossible to achieve coherent output due to self-heating of the nanolaser,” Andrey Vyshnevyy adds.

Therefore, it is highly important to distinguish the illusive lasing threshold from the actual one. While both the coherence measurements and the calculations are difficult, Vyshnevyy and Fedyanin came up with a simple formula that can be applied to any nanolaser. Using this formula and the output characteristic, nanolaser engineers can now rapidly gauge the threshold current of the structures they create.

The findings reported by Vyshnevyy and Fedyanin enable predicting in advance the point at which the radiation of a nanolaser — regardless of its design — becomes coherent. This will allow engineers to deterministically develop nanoscale lasers with predetermined properties and guaranteed coherence.

Intentionally “squashing” colloidal quantum dots during chemical synthesis creates dots capable of stable, “blink-free” light emission that is fully comparable with the light produced by dots made with more complex processes. The squashed dots emit spectrally narrow light with a highly stable intensity and a non-fluctuating emission energy. New research at Los Alamos National Laboratory suggests that the strained colloidal quantum dots represent a viable alternative to presently employed nanoscale light sources, and they deserve exploration as single-particle, nanoscale light sources for optical “quantum” circuits, ultrasensitive sensors, and medical diagnostics.

“In addition to exhibiting greatly improved performance over traditional produced quantum dots, these new strained dots could offer unprecedented flexibility in manipulating their emission color, in combination with the unusually narrow, ‘subthermal’ linewidth,” said Victor Klimov, lead Los Alamos researcher on the project. “The squashed dots also show compatibility with virtually any substrate or embedding medium as well as various chemical and biological environments.”

The new colloidal processing techniques allow for preparation of virtually ideal quantum-dot emitters with nearly 100 percent emission quantum yields shown for a wide range of visible, infrared and ultraviolet wavelengths. These advances have been exploited in a variety of light-emission technologies, resulting in successful commercialization of quantum-dot displays and TV sets.

The next frontier is exploration of colloidal quantum dots as single-particle, nanoscale light sources. Such future “single-dot” technologies would require particles with highly stable, nonfluctuating spectral characteristics. Recently, there has been considerable progress in eliminating random variations in emission intensity by protecting a small emitting core with an especially thick outer layer. However, these thick-shell structures still exhibit strong fluctuations in emission spectra.

In a new publication in the journal Nature Materials, Los Alamos researchers demonstrated that spectral fluctuations in single-dot emission can be nearly completely suppressed by applying a new method of “strain engineering.” The key in this approach is to combine in a core/shell motif two semiconductors with directionally asymmetric lattice mismatch, which results in anisotropic compression of the emitting core.

This modifies the structures of electronic states of a quantum dot and thereby its light emitting properties. One implication of these changes is the realization of the regime of local charge neutrality of the emitting “exciton” state, which greatly reduces its coupling to lattice vibrations and fluctuating electrostatic environment, key to suppressing fluctuations in the emitted spectrum. An additional benefit of the modified electronic structures is dramatic narrowing of the emission linewidth, which becomes smaller than the room-temperature thermal energy.

Samsung Electronics Co., Ltd. today introduced its latest innovations in modular MicroLED display technology during its annual First Look CES event at the Aria Resort & Casino in Las Vegas. The revolutionary new MicroLED technology designs featured at the event included: a new 75” display, a 219” The Wall as well as other various groundbreaking sizes, shapes and configurations for a next-generation modular MicroLED display – a 2019 CES Best of Innovation Award winner.

“For decades, Samsung has led the way in next-generation display innovation,” said Jonghee Han, President of Visual Display Business at Samsung Electronics. “Our MicroLED technology is at the forefront of the next screen revolution with intelligent, customizable displays that excel in every performance category. Samsung MicroLED has no boundaries, only endless possibilities.”

Featuring self-emissive technology and modular capabilities, Samsung’s MicroLED displays deliver unparalleled picture quality, versatility and design. These transformative TV displays are made up of individual modules of self-emissive MicroLEDs, featuring millions of inorganic red, green and blue microscopic LED chips that emit their own light to produce brilliant colors on screen – delivering unmatched picture quality that surpasses any display technology currently available on the market.

At last year’s CES, Samsung introduced MicroLED by unveiling The Wall, the critically acclaimed, award-winning 146” MicroLED display. Due to the technical advancements in the ultra-fine pitch semiconductor packaging process that narrow the gap between the microscopic LED chips, Samsung has been able to create a stunning 4K MicroLED display in a smaller, more home-friendly 75” form factor.

Thanks to the modular nature of MicroLED, this technology offers flexibility in screen size that allows users to customize it to fit any room or space. By adding MicroLED modules, users can expand their display to any size they desire. The modular functionality of MicroLED will allow users in the future to create the ultimate display even at irregular 9×3, 1×7 or 5×1 screen sizes that suits their spatial, aesthetic and functional needs.

Samsung’s MicroLED technology also optimizes the content no matter the size and shape of the screen. Even when adding more modules, Samsung MicroLED displays can scale to increase the resolution — all while keeping the pixel density constant. Additionally, MicroLED can support everything from the standard 16:9 content, to 21:9 widescreen films, to unconventional aspect ratios like 32:9, or even 1:1 – without having to make any compromises in its picture quality.

Finally, because MicroLED displays are bezel-free, there are no borders between modules – even when you add more. The result is a seamless, stunning infinity pool effect that allows the display to elegantly blend into any living environment. The possibilities for eye-catching designs are enhanced by new Ambient Mode features.

For more detail on Samsung’s 2019 QLED 8K and MicroLED lines, please visit booth #15006 in the Central Hall of the Las Vegas Convention Center during CES 2019 (January 8-11, 2019).

An international team of researchers has developed a technique that, for the first time, allows single-crystal hybrid perovskite materials to be integrated into electronics. Because these perovskites can be synthesized at low temperatures, the advance opens the door to new research into flexible electronics and potentially reduced manufacturing costs for electronic devices.

Hybrid perovskite materials contain both organic and inorganic components and can be synthesized from inks, making them amenable to large-area roll-to-roll fabrication. These materials are the subject of extensive research for use in solar cells, light-emitting diodes (LEDs) and photodetectors. However, there have been challenges in integrating single-crystal hybrid perovskites into more classical electronic devices, such as transistors.

Single-crystal hybrid perovskites are preferable because single-crystalline materials have more desirable properties than polycrystalline materials; polycrystalline materials contain more defects that adversely affect a material’s electronic properties.

The challenge in incorporating single-crystal hybrid perovskites into electronics stems from the fact that these macroscopic crystals, when synthesized using conventional techniques, have rough, irregular edges. This makes it difficult to integrate with other materials in such a way that the materials make the high-quality contacts necessary in electronic devices.

The researchers got around this problem by synthesizing the hybrid perovskite crystals between two laminated surfaces, essentially creating a single-crystal hybrid perovskite sandwich. The perovskite conforms to the materials above and below, resulting in a sharp interface between the materials. The substrate and superstrate, the “bread” in the sandwich, can be anything from glass slides to silicon wafers that are already embedded with electrodes – resulting in a ready-made transistor or circuit.

The researchers can further fine-tune the electrical properties of the perovskite by selecting different halides for use in the perovskite’s chemical make-up. The choice of halide determines the bandgap of the material, which affects the color appearance of the resulting semiconductor and leads to transparent and even imperceptible electronic devices when using high-bandgap perovskites.

“We have demonstrated the ability to create working field-effect transistors using single-crystal hybrid perovskite materials fabricated in ambient air,” says Aram Amassian, corresponding author of a paper on the work and an associate professor of materials science and engineering at NC State.

“That’s of interest because traditional single-crystal materials have to be manufactured in ultra-high vacuum, high-temperature environments, and often require exquisite epitaxial growth,” Amassian says. “Hybrid perovskites can be grown from solution, essentially from an ink, in ambient air at temperatures below 100 degrees Celsius. This makes them attractive from a cost and manufacturing standpoint. It also makes them compatible with flexible, plastic-based substrates, meaning that they may have applications in flexible electronics and in the internet of things (IoT).

“That said, there are still major challenges here,” Amassian says. “For example, current hybrid perovskites contain lead, which is toxic and therefore not something that’s desirable for applications like wearable electronics. However, research is ongoing to develop hybrid perovskites that don’t contain lead or that are even entirely metal-free. This is an exciting area of research, and we feel this work is a significant step forward for the device integration of these materials, leading to the development of new technological applications.”

Seoul Semiconductor Co., Ltd. (KOSDAQ:046890) (“Seoul”), a developer of LED products and technology, announced that it won a patent litigation against Everlight Electronics Co., Ltd. (“Everlight”) in Germany.

The patent involved in this litigation relates to an LED package structure for thermal dissipation. Everlight purchased this patent from a U.S. company in 2017, and subsequently brought a patent lawsuit against Seoul in the Manheim Court of Germany.

In December 2018, however, the Manheim Court ruled in favor of Seoul and ordered that Everlight, as the losing party, should bear the statutory costs of the court proceeding.

In the United Kingdom, Seoul had already won a patent litigation against Everlight earlier this year. At that time, the UK Patent Court also ordered that Everlight must pay approximately one million dollars in litigation costs to Seoul. In the meantime, Seoul is pursuing patent infringement lawsuits against a global distributor of Everlight’s high-power and mid-power LED products in Germany, Italy and Japan.

Everlight has previously sued another of its competitors in Japan after purchasing a patent from a foreign company, but it lost that action as well. In April 2017, Everlight filed a patent lawsuit against Nichia Corporation and Citizen Electronics in Japan, relying on the purchased-patent. However, the Tokyo District Court dismissed Everlight’s lawsuit in October 2018.

“Seoul has invested approximately 100 billion won per year in research and development to ensure that it creates its own cutting-edge technology and products, thereby establishing its own formidable patent portfolio,” said Nam Ki-bum, Executive Vice President of the Lighting Department at Seoul. “We hope that our commitment and success for technology innovation would inspire young entrepreneurs and small businesses.”

The ideal optoelectronic semiconductor material should be a strong light emitter i.e. should emit light very efficiently upon optical excitation as well as be an efficient charge conductor to allow for electrical injection in devices. These two conditions when met can lead to highly efficient light emitting diodes as well as to solar cells with the possibility to approach the Shockley-Queisser limit. Until now the materials that have come close to meeting these conditions have been based on epitaxially-grown costly III-V semiconductors that cannot be monolithically integrated to CMOS electronics.

The ICFO team has reported a solution processed nanocomposite system comprising infrared colloidal quantum dots that also meets these criteria and at the same time offers low cost and facile CMOS integration. Colloidal Quantum Dots (CQDs) are extremely small semiconductor particles or crystals, as small as a few nanometers in size, and because of their size they are capable of having unique optical and electronic properties. They are excellent absorbers and emitters of light, having their properties change as a function of their size and shape: smaller quantum dots emit in the blue range while larger quantum dots emit in the red.

The use of colloidal quantum dot (CQD) light-emitting diodes (LEDs) has become one of the key ingredients in leading technologies such as, for example, 3rd generation, solution processed, and inorganic solar cells. The implementation of these nanocrystals in devices for optical sensing in the short-wave and mid- infrared have triggered a vast number of applications including surveillance, night vision, product, process and environmental monitoring and spectroscopy.

In this recent study published in Nature Nanotechnology, ICFO researchers Santanu Padhan, Francesco Di Stasio, Yu Bi, Shuchi Gupta, Sotirios Christodoulou, and Alexandros Stavrinadis, led by ICREA Prof. at ICFO Gerasimos Konstantatos, have developed CQD infrared emitting LEDs, which have achieved unprecedented values in the infrared range, with an external quantum efficiency of 7.9% and a power conversion efficiency of 9.3%, a value never attained before with these type of devices.

The key feature of this work has been the development of a CQD composite structure engineered at the suprananocrystalline level to reach unprecedently low electronic defect density. Prior efforts in suppressing electronic defects in CQD solids have been primarily been based on chemical passivation of the CQD surface, something that could not solve the problem in PbS QDs. The researchers at ICFO took an alternative path of creating the appropriate matrix in which they embedded the emitting QDs, to serve as a remote electronic passivant for the emitter CQDs. Moreover, the energetic landscape of the matrix was engineered in order to facilitate efficient charge funnelling into the QD emitters in order to achieve efficient electrical injection.

With these new blend devices, the team of researchers took a step further and constructed solar cells to test their performance in the infrared range. In doing so they discovered that the effective passivation achieved in these nanocomposites along with the modulation of the electronic density of states has resulted in solar cells that deliver open circuit voltage very close to the theoretical limit. The open circuit voltage (VOC), which is the maximum voltage available from a solar cell, increased from 0.4 V for a single QD configuration, up to ~0.7 V for the ternary blend configuration, an impressive value considering the lower bandgap of the cell at ~0.9 eV.

As ICREA Prof at ICFO Gerasimos Konstantatos comments, “The most surprising finding of this study is the extremely low electronic trap density that can be achieved in a conductive QD material system that is full of chemical defects arising on the surface of the dots, the very high quantum efficiency of those LEDs has been the consequence of this passivation strategy we demonstrate. The other exciting outcome has been the potential to reach so high Voc values for QD solar cells that was synergistically achieved thanks to the very low trap density as well as to a novel engineering approach of the density of states in a semiconductor film”. Santanu Pradhan, the first author of this study adds: “Next we will focus on how to further exploit this reduction of electronic density of states synergistically with other means to allow for simultaneous achievement of high Voc and current production, thereby targeting record power conversion efficiencies in solar cell devices”.

The results obtained in this study prove that the engineering of QCD infrared-emitting LEDs at the nanoscale integrated in solar cells can significantly improve the performance efficiency of these devices in the infrared range. Such results open the pathway into a range of the spectra that is still to be fully exploited and offers amazing new applications, such as on-chip spectrometers for food inspection, environmental monitoring, manufacturing process monitoring as well as active imaging systems for biomedical or night vision applications.