Category Archives: Photoresist

67237

Lithography


January 6, 2016

The process of creating a pattern on a wafer is known as lithography. Typically, light is shone through a mask onto a photoresist that coats the wafer. After exposure, the photoresist is “developed,” which removes the exposed part of the resist (or the unexposed resist if it is negative resist). A photoresist coat/bake/develop system — often called a “track system” is typically connected directly to the wafer exposure tool or wafer “stepper.”

The exposed wafer is then etched, where the photoresist acts as a barrier to the etching chemicals or reaction ions. The photoresist is then removed by stripping or “ashing.” In complex integrated circuits, a modern CMOS wafer will go through the photolithographic cycle up to 50 times, making lithography one most critical process step.

Increasingly smaller wavelengths of light have been used to create smaller dimensions. Complex mask designs have also evolved, such as optical proximity correction (OPC), to correct for optical effects. Mask-source optimization techniques have also been developed to correct for variations in the source and on the wafer.

A push to extreme ultra-violet (EUV) lithography has been under way for a decade or more, led by ASML Lithography. Alternatives have also been research and developed, including nano-imprint lithography (NIL), which uses stencils and multi e-beam (MEB) lithography, which uses a large bank of individually controlled electron beams to expose the wafer directly (no mask required). More recently, an interesting approach called directed self-assembly (DSA) has been studied, which enables very small dimensions. DSA uses a guide structure on the wafer and polymer-based chemicals to create regular lines with very small dimensions.

Check out our Lithography Topic Center for regular updates.

Additional Reading:

Feed-forward overlay control in lithography processes using CGS

Advanced lithography and electroplating approach to form high-aspect ratio copper pillars

EUV lithography is on the threshold of becoming a mainstream patterning technology for sub-10nm chips, featured speaker Anthony Yen of Taiwan Semiconductor Manufacturing Co. (TSMC) will tell fellow attendees at SPIE Advanced Lithography 2016.

SPIE Litho will run February 21-25 in the San Jose (California) Marriott and Convention Center, and is sponsored by SPIE, the international society for optics and photonics.

In its 41st year in 2016, the annual event provides a focal point for the development of micro- and nanolithography and related technologies. It brings together participants from a wide range of sectors to share and learn about state-of-the-art lithographic tools, resists, metrology, materials, etch, design, and process integration.

Yen, a former SPIE Litho symposium chair and the director of TSMC’s Nanopatterning Technology Infrastructure Division, is one of three leading semiconductor lithography researchers scheduled to give plenary talks on Monday of the conference week.

Harry Levinson, GlobalFoundries Senior Director of Technology Research and Senior Fellow and another former SPIE Litho symposium chair, will review the evolution of lithographic technologies in his plenary talk, starting with the earliest simulation software through to EUV.

Richard Gottscho, Executive vice president of Global Products at Lam Research Corporation, will discuss how to minimize process-induced variability in multiple patterning.

SPIE Litho will offer more than 500 presentations in seven conferences, two poster receptions, 15 technical professional development courses, a two-day exhibition showcasing leading suppliers for the industry, and the first-ever SPIE Litho all-symposium welcome reception.

Mircea Dusa, Fellow and scientist at ASML US, Inc., is symposium chair, and Bruce Smith, Director of Microsystems Engineering at Rochester Institute of Technology, is cochair.

Among other highlights are:

  • the 30th anniversary celebration for the Metrology, Inspection, and Process Control conference with a “Wheel of Fortune” game
  • awarding of the 2016 SPIE Frits Zernike Award for Microlithography
  • a panel discussion on fundamental technology challenges in metrology, lithography, and design as critical dimensions for integrated circuits shrink to near-atomic scales.

Companies in the exhibition on Tuesday and Wednesday will include Canon USA, Inc., Carl Zeiss SMS GmbH, JSR Micro, Inc., Swiss Litho AG, Synopsys, Inc., Tokyo Electron Limited, Zygo Corporation, and others, both well-established industry leaders and newer companies.

Accepted conference proceedings papers will be published in the SPIE Digital Library as soon as approved after the meeting, and in print volumes and digital collections.

Registration, hotel, and other information is at www.SPIE.org/AL.

SPIE is the international society for optics and photonics, an educational not-for-profit organization founded in 1955 to advance light-based science and technology. The Society serves nearly 264,000 constituents from approximately 166 countries, offering conferences and their published proceedings, continuing education, books, journals, and the SPIE Digital Library in support of interdisciplinary information exchange, professional networking, and patent precedent. In 2015, SPIE provided more than $5.2 million in support of education and outreach programs. SPIE is a Founding Partner of the International Year of Light and Light-based Technologies and a Founding Sponsor of the U.S. National Photonics Initiative.

Feed-forward can be applied for controlling overlay error by using Coherent Gradient Sensing (CGS) data to reveal correlations between displacement variation and overlay variation.

BY DOUG ANBERG and DAVID M. OWEN, Ultratech, San Jose, CA

As the semiconductor industry is fast approaching 10nm design rules, there are many difficulties with process integration and device yield. Lithography process control is expected to be a major challenge requiring overlay control to a few nanometers. There are many factors that impact the overlay budget that can be broadly categorized as those arising from the reticle, the lithography tool and wafer processing. Typically, overlay budget components associated with the reticle and lithography tool can be characterized and are relatively stable. However, as published elsewhere, process-based sources of surface displacement can contribute to the lithography overlay budget, independent of the lithography process (e.g., etch, anneal, CMP). Wafer-shape measurement can be implemented to characterize process-induced displacements. The displacement information can then be used to monitor specific processes for excursions or be modeled in terms of parameters that can be fed-forward to correct the lithography process for each wafer or lot.

The implementation of displacement feed-forward for overlay control requires several components, including: a) a system capable of making comprehensive surface displacement measurements at high throughput, b) a characterization and understanding of the relationship between displacement and overlay and the corresponding displacement variability, c) a method or system to integrate the displacement information with the lithography control system. The Coherent Gradient Sensing (CGS)technique facilitates the generation of high-density displacement maps (>3 million points on 300mm wafers) such that distortions and stresses induced shot-by-shot and process-by-process can be tracked in detail. This article will demonstrate how feed forward can be applied for controlling overlay error by using CGS data to reveal correlations between displacement variation and overlay variation.

High-speed, full-wafer data collection

Historically, patterned wafer surface inspection was limited to monitoring topography variations within the die area and across the wafer with the use of point-by-point measurements with low throughput, typically limiting measurements to off-line process development. Surface inspection of patterned wafers involving transparent films (e.g. SiO2 deposited films) was typically further limited to contact techniques such as stylus profilometry.

With CGS interferometry, a high-resolution front-surface topography map of a full 300 mm patterned wafer can be obtained for product wafers with an inspection time of a few seconds. Transparent films can typically be measured successfully without opaque capping layers due to the self-referencing attribute of the CGS interferometer. Essentially, CGS technology compares the relative heights of two points on the wafer surface that are separated by a fixed distance. Physically, the change in height over a fixed distance provides slope or tilt information and the fringes in a CGS interference pattern are contours of constant slope. In order to reconstruct the shape of the surface under investigation, interference data in two orthogonal directions must be collected. The slope data derived from the interference patterns is integrated numerically to generate the surface shape or topography. In-plane surface displacements in the x- and y-directions can then be computed from the surface topography using fundamentals of plate theory (FIGURE 1).

Fig 1-a Fig 1-b Fig 1-c

FIGURE 1. Example of the analysis of the uniform and non-uniform stress components of the displacement field: (a) total displacement computed from the x-direction slope, (b) uniform stress component of the displacement field determined from the best-fit plane to the data in (a), (c) non- uniform stress component of the displacement field.

To best utilize the capabilities of CGS technology for determining stress-induced displacement impacting critical layer overlay budgets, a “Post minus Pre” inspection strategy is typically employed, where two measurements of a wafer are taken: one prior to the process step or module of interest (the pre-process map), and a second measurement is taken on the same wafer after completing the process step or module (the post-process map). The pre-process topography map is then mathematically subtracted from the post-process topography map, providing detailed, high resolution information about the topography variation in the process step or module of interest. A series of topography maps illustrating the “Post minus Pre” process is shown in FIGURE 2.

FIGURE 2. Example of “Post minus Pre” topography CGS measurement.

FIGURE 2. Example of “Post minus Pre” topography CGS measurement.

The surface displacements directly impact the relative position of all points on the wafer surface, leading to potential alignment errors across the wafer at the lithography step. By measuring the evolution of process-induced stresses and displacement across multiple steps in a process flow, the overlay error due to the accumulated stress changes from those process steps can be evaluated, and the cumulative displacement can be calculated. The displacement error can then be fed forward to the lithography tool for improved overlay correction during the exposure process.

In the simplest implementation of this approach, the pre-process or reference measurement would be made following the prior lithography step, whereas the post- processing measurement would be made just before the lithography step of interest. In this manner, the total displacement induced between two lithography steps can be characterized and provided to the lithography system for overlay correction.

Stress and displacement process fingerprinting

By using CGS-based inspection to generate full-wafer topography, displacement and stress, detailed information can be provided for both off-line process monitoring (SPC), or in-line, real-time monitoring (APC) of process steps with significant process induced stress and displacement. A key consequence of the monitoring flexibility afforded by the measurement is the ability to characterize and compare within- wafer displacement and stress fingerprints of individual process chambers in a manufacturing line.

Target-based overlay metrology systems have historically been used as the only metrology tool to measure overlay error at critical lithography layers. Overlay data from the target-based overlay tools is collected after the wafer exposure step and is fed-backward to correct for the measured overlay error for subsequent wafers. As process- induced displacement errors are becoming a significant percentage of the layer-to-layer overlay budget, this post processing feed-back approach for overlay correction may not be sufficient to meet critical layer overlay specifications. Furthermore, overlay errors are often larger near the edge of the wafer where traditional overlay metrology target densities are typically low, providing only limited data for overlay correction.

The implementation of displacement feed-forward overlay correction can be
used to account for wafer-to-wafer and within-wafer distortions prior to lithography. The displacements can be characterized using an appropriate model and the model coefficients, or correctables, can be provided to the lithography tool for adjustment and control on a wafer-by-wafer basis. As shown in FIGURE 3, the CGS technique has the additional advantage of providing high-data density near the edge of the wafer (typically > 75,000 data points beyond 145 mm, sub-sampled in the Fig. 3 vector map for clarity), such that more accurate corrections can be determined where the overlay errors tend to be largest. As a result, lithography rework can be reduced and productivity increased. Case studies have revealed that a significant improvement in overlay can be achieved using this approach.

FIGURE 3. Vector displacement map showing process-induced edge distortion.

FIGURE 3. Vector displacement map showing process-induced edge distortion.

For each critical lithography step, a correlation is typically generated by comparing the traditional overlay measurement tool results to the surface displacement measured by the CGS measurement tool. Recognizing that displacement is only one component of the total overlay measurement, correlation of overlay to displacement requires effort to model or characterize the non-displacement components of the measured overlay. As a result, the appropriate correlation is derived by comparing total overlay to displacement plus the non-displacement overlay sources.

FIGURE 4 shows plots of total overlay versus displacement plus modeled non-displacement overlay sources for multiple locations on a single wafer processed in a leading-edge device flow. Figure 4a shows the x-direction data, whereas Fig. 4b shows the y-direction data. The data is presented in arbitrary units, however the same reference value in nanometers was used to normalize each set of data. The displacement data was evaluated at the same locations as the overlay target positions. For both the x-direction and y-direction data, the point-to-point correlation indicates good correlation with the correlation coefficients of 0.70 and 0.76, respec- tively. The RMS of the residuals of the linear fit to each data set are on the order of 1.5 to 2.0 nm.

Fig 4a

Fig 4b

FIGURE 4. Within-wafer (point-to-point) correlation of conventional overlay data and displacement data for the (a) x-direction and (b) y-direction.

FIGURE 5 similarly shows the wafer-to-wafer variation for overlay and displacement for the x-direction (Fig. 5a) and y-direction (Fig. 5b). The data in Fig. 5 are from multiple lots for the same lithography process evaluated to generate the data in Fig. 4. As with the point-to-point data, the wafer-to-wafer data shows strong correlation with correlation coefficients of 0.94 and 0.90 for the x-direction and y-direction, respectively.

Fig 5a Fig 5b

FIGURE 5.Wafer-level correlation between conventional overlay, |mean| + 3 sigma and displacement, |mean| + 3 sigma for a leading-edge process in the (a) x-direction and (b) y-direction.

The data in Figs. 4 and 5 illustrate key points regarding the correlation of overlay to displacement. First, the inherent variability of an advanced lithography process is typically on the order of 1 to 2nm. As a result, it is reasonable to conclude that the most of the scatter shown in Fig. 4 is likely associated with the variability in non-displacement sources of overlay variation. Second, the modeling or empirical characterization of non-displacement overlay sources is useful to the extent to which those non-displacement sources are constant. Consequently, if such modeling is part of the displacement feed-forward scheme in an effort to predict overlay, the model must account for known variations in the lithography process. A simple example is varia- tions in overlay performance due to differences between lithography chucks.

Displacement feed forward

It has been shown elsewhere that stress induced displacement can account for a significant fraction of the overlay error for certain critical layers at the 40nm node and below. It is therefore critical to develop the tools necessary for utilizing the measured displacement data for real-time in-line feed forward overlay correction to the scanner. One approach to this solution is to develop a system that allows the user to define the level of correction to be applied to the scanner for each lot, wafer or within-wafer zone.

FIGURE 6 shows a simplified schematic for a combined displacement feed-forward and image placement error feed-back approach. Once the process induced displacement for a specific set of process steps has been measured and correlated to overlay error, the measured displacement can be “fed forward” to the scanner in combination with traditional image placement error feedback techniques to further improve critical layer scanner overlay results. This approach is currently being implemented in leading-edge memory fabs to further reduce overlay errors on critical lithography levels and improve overall device yield.

Summary

The measurement of process-induced surface displacement can be an effective part of the overlay control strategy for critical layers at leading edge process nodes. CGS technology provides a method to comprehensively measure these displacements at any point in the process flow. Using a full-wafer interferometer, this system measures the patterned wafer surface in a few seconds and provides a map with up to 3,000,000 data points. This enables 100% in-line monitoring of individual wafers for in-situ stress and process induced surface displacement measurements. Its self-referencing interferometer allows the inspection to be made on any type of surface or films stack, and does not require a measurement target. This capability is currently being employed in numerous leading-edge memory and logic processes.

DOUG ANBERG currently serves as Ultratech’s Vice President of Advanced Lithography Applications; DAVID M. OWEN has been the Chief Technologist for Surface Inspection at Ultratech since 2006. Prior to joining Ultratech, Dr. Owen spent nearly a decade as a research scientist at the California Institute of Technology (Caltech) in Pasadena, and was the Founder and Chief Technology Officer for Oraxion Diagnostics.

It is possible to fabricate copper pillars more than 100μm in height, with aspect ratios up to 6:1, using advanced packaging stepper lithography in conjunction with electroplating.

BY KEITH BEST, Rudolph Technologies, Wilmington, MA, and PHILLIP HOLMES, TEL NEXX, Billerica, MA

Recent years have seen rapid development in the area of advanced packaging. In general, advanced packaging processes are concerned with the interconnection of multiple chips in a single package to provide increased functionality and performance in a smaller volume. System Scaling Technology — the combination of front-end, middle-end and back-end to advance microelectronic systems—utilizes many different advanced packaging approaches, one of which is known as 2.5D packaging. The term “2.5D packaging” has not always been used consistently in literature. The definition used for the purpose of this paper can be summarized as follows: a 2.5D package utilizes an interposer between multiple silicon die and a system-in-package (SiP) substrate, where this interposer has through vias connecting the metallization layers on its front and back surfaces (FIGURE 1).

FIGURE 1. A 2.5D IC/SiP using an interposer and through vias.

FIGURE 1. A 2.5D IC/SiP using an interposer and through vias.

 

The development of these new packaging schemes is being driven primarily by the rapid growth in mobile handheld devices such as smartphones. Often, the manufacturing processes used are adaptations of well-established front-end processes. A number of different approaches are in development or already in production, including wafer-level chip scale packaging, copper pillar bumps on through silicon vias (TSVs), fan-out wafer level processing, and many more. Of particular interest is the replacement of solder bumps by fine pitch copper pillar bumps, which has been the subject of many new system- in-package designs. Here we investigate the lithography and plating of copper pillars, with focus on heights in excess of 100μm and diameters of 25μm, in anticipation of future SiP requirements.

The increase in the number of I/O channels required by multi-chip system designs has exceeded the density and pitch capabilities that traditional solder bump processes can deliver, so that an alternative connection scheme is required. For interposers, the key enabling technology has been the development of fine pitch copper pillar bumps to provide the high-density interconnection between the interposer and the die. Copper pillar bumps provide a number of advantages over the solder bumps they are supplanting. They can deliver finer pitches, 40μm and less have been demonstrated. They also provide superior electromigration performance in applications where high current-carrying capacity is required. However, lithography and electroplating for fine pitch copper pillar bumps can be particularly challenging. The pillars are electroplated into openings in a thick layer of photoresist which exceeds the capability of most front-end tools. Typically, today’s copper pillars range from 30-50μm in height, with height to width aspect ratios from 1:1 to around 2:1 Here we describe the lithography, resist, and electroplating systems and processes required to create 5:1 aspect ratio copper pillars with heights in excess of 100μm.

Photoresist

A negative tone photoresist (JSR THB-151N) was chosen for this work. Its acrylate groups cross-link on exposure and are developed in industry standard 2.38% TMAH developer. The photoresist was spun to a thickness of 120μm on 300mm silicon wafers with an under bump metallization (UBM) prepared seed layer. To reach the 120μm photoresist film thickness, two coatings of photoresist were required, soft baked at 130C, 300secs and 130C, 360secs respectively. After coating, the photo- resist film was allowed to rehydrate for one hour prior to exposure on a wafer stepper (Rudolph Technologies’ JetStep System).

Lithography

We used a customized test reticle that included a wide range of sizes and pitches to expose the wafer. When processing a thick photoresist, well-controlled sidewall angles are a critical requirement, especially when electroplating tall copper pillars. Most front-end tools have high numerical aperture (NA) lenses with low depth of focus (DOF) that prevent adequate exposure of thick films with sufficient image contrast to meet the sidewall angle and resolution requirements. Mask aligners also struggle with high aspect ratio imaging, not because of their NA, but because they are unable to provide the necessary focus offset required to expose the film at high resolution, ultimately limiting their aspect ratio and sidewall angle control. Although photoresist sidewall angles are primarily a function of the photoresist material and its processing (pre-bake, post-bake, developing, etc.), the exposure system plays an important role. Accurate focus control across the wafer or substrate is required to achieve consistent and accurate CD control with straight and perpendicular sidewalls.

The lithography stepper employed in this study refocuses for each exposure to ensure optimal focal plane height on advanced packaging substrates that are frequently warped by film stress and thermal cycling. The system’s 0.1 NA provides a large depth of focus to maintain image integrity and CD control through thick films. The stepper lens is achromatized and the installed “filter wheel” provides a choice of illumination wavelengths to expose the photoresist layers: “broadband” ghi (350-450nm), gh (390 to 450nm) or i-line (365nm). This study, with a photoresist thickness of 120μm, required high energy illumination of >1000 mJ/cm<sup>2</sup>, so broadband illumi- nation (g,h,i wavelengths) was employed to maintain high throughput.

The coated wafers were exposed using a focus exposure matrix wafer layout which provided a large number of programmed focus and exposure conditions at a fixed stepping distance to enable quick and efficient character- ization of the lithography process window for any pillar CD. After exposure, the wafers were developed for a total time of 180 secs, using 6 puddles in 2.38% TMAH. A number of wafers were processed in this way to provide images of the resist structures prior to the electroplating process. The SEM micrograph in FIGURE 2 shows a cross section of the photoresist via mold structures, the CD limit appears to be 25μm with this process, since the via is not open to the seed metal beyond this resolution.

lithography 2

It is interesting to note how the sidewall angle of the photoresist changes with decreasing CD suggesting that the plating will generate a “pedestal” type of copper pillar base at larger CDs, becoming progressively more vertical at smaller CDs. However, upon closer inspection of the smallest CDs, a slight “footing” can be observed at the base of the via (FIGURE 3), and this could result in slight undercut of the final copper pillar. The footing effect was most likely the result of our unoptimized develop process.

lithography 3

Electroplating

After the lithography processing, the wafers were sent to TEL NEXX for electroplating. The plating process employed the TEL NEXX Stratus P300 System, a fully automated electrochemical deposition system for advanced wafer-level packaging applications. The system deposits thick metal layers for wafer bumping, redistribution layers, TSVs, integrated passives, and MEMS.

In this study, we used a methanesulfonic acid copper chemistry with organic additives. The bath composition, operating temperature and current waveform were optimized for high speed copper plating into very thick resist features with flat bump profiles. After plating the photoresist was stripped using an immersion bath with EKC162 solution at 60 degrees. To preserve the profile of the photoresist mold the seed layer was not etched. The final copper pillar structures exhibit the inverse photo- resist mold profile (FIGURE 4).

lithography 4

The electroplating process successfully deposited copper in the photoresist via “molds” that were open to the copper seed material, producing good quality copper pillars with a final minimum copper pillar CD of 20μm, indicating a process bias of 5μm. This bias enabled the final copper pillar to reach a 6:1 aspect ratio as shown in FIGURE 5.

lithography 5

The final copper pillars exhibit excellent sidewall angle, 90 degrees for the smaller CDs. The profiles correlate well with the profiles observed in the photoresist SEM cross sections. The change in profile at the base of the photoresist for the smaller CDs did result in a slight undercut of the final copper pillar. The removal of this photoresist foot could be achieved by either increasing the de-scum time or modifying the develop recipe. The larger copper pillars tended to flare out slightly at the base (FIGURE 6) compensating for any undercut. This will benefit the structure during the removal of the copper seed layer.

lithography 6

The rheology of the copper pillar surface is very important for bonding reliability and the uniform plating of Sn solder, which was not performed during this particular study since it was not the primary objective. FIGURE 7 shows the flat top surface of a copper pillar which is free of voids and defects.

lithography 7

For advanced packaging applications, precise copper pillar height control is essential, and lithography CD control plays an important part in the plating process since CD variation directly affects plated height. The electroplating rate is proportional to current per unit area, i.e. the open area at the bottom of the photoresist openings at the beginning of the process, and the area of the evolving metal surface during deposition. Variation in CD or sidewall angle across the wafer will result in a corresponding change in copper pillar height. For example, in the case of copper pillar features a 5% change in CD can cause a 10% change in plated height.

Conclusion

The results of this study prove that it is possible to fabricate copper pillars more than 100μm in height, with aspect ratios up to 6:1, using advanced packaging stepper lithography in conjunction with electroplating. As advanced packaging requirements continue to evolve, the ability to create smaller copper pillar CDs at finer pitches in thick films will provide increased I/O density opportunities for SiP designers. Furthermore, it is clear that achieving high yield and reliability in the final package requires precise CD control throughout the entire photoresist profile to ensure consistent copper pillar height.

KEITH BEST is director applications engineering at Rudolph Technologies, Wilmington, MA. PHILLIP HOLMES is director of technology at TEL NEXX, Billerica, MA

Vistec Electron Beam GmbH, a supplier of electron-beam lithography systems, announced that it has established a show room facility in Schaumburg, IL to promote and demonstrate their Variable Shaped Beam systems specifically for the US and North America market.

The show room facility in Schaumburg is designed to demonstrate the functionality and operation of Vistec’s ebeam equipment and to provide an insight into its various applications. The key component of the facility is a fully operational Vistec SB254 electron-beam lithography system, installed in a clean room of 970sqft., supplemented by a set of process and measurement equipment for standard sample processing.

“We are very pleased to be able to offer such a demonstration capability to potential North America market customers. The availability of the show room facility shall manifest our commitment to this important high technology region, it will foster our activities to better understand customer needs and shall help to provide tailored solutions to their specific requirements,” said Wolfgang Dorl, General Manager of Vistec Electron Beam.

The availability of patterning alternatives in the lithography landscape represents a big opportunity to properly address the coming needs generated by the IoT.

BY LAURENT PAIN, RALUCA TIRON, LUDOVIC LATTARD, STEFAN LANDIS and CYRILLE LAVIRON, CEA-Leti, Grenoble, France

The Internet of Things (IoT) is expected to fuel significant growth opportunities for the semiconductor industry, as demand increases for wireless components and more and more embedded functionalities such as memory and sensors. This growth will affect almost all integrated circuit (IC) sectors (FIGURE 1). The chip industry will continue to need advanced technologies to provide the most powerful functionalized ICs with lower power consumption for the IoT, but manufacturing costs remain a key challenge. Lithography and related patterning technologies can represent up to 50 percent of total IC production costs, and significant efforts have to be made in the coming years to slow and even reverse this trend.

Litho Fig 1

In the lithography landscape for the development of advanced technology nodes, extreme-UV (EUV) lithography technology recovered some credibility at the beginning of 2015 with the release and installation of the first 80W power sources[1]. However, its adoption by the industry remains uncertain, because its infrastructure still requires significant development. Also, the recurrent questions about the real cost of ownership associated with the ability of the 0.33NA platform to address sub-7nm technology nodes continue to dominate the debate in the semiconductor community, especially since 3D-stacking strategies are being seriously investigated. This potentially could slow demand for high-resolution and therefore delay the new advanced lithography solutions.

Meanwhile, 193nm immersion lithography, with double- or quadruple-patterning strategies, supports the industry preference for advanced-node developments, despite the tremendous effort required for process controls (alignment, mask manufacturing etc.). In this landscape, lithography alternatives maintain promise for continued R&D because they may present competitive compromises for the industry. Massively parallel electron-beam and nano-imprint lithography techniques remain highly attractive, as they can provide noteworthy cost-of-ownership benefits for IC manufacturers. In addition, directed self-assembly (DSA) lithography with block copolymer shows promising resolution capabilities and appears to be an option to reduce multi-patterning strategies, and therefore the associated mask-set budgets. But what is the current status of these technologies? Are they really able to meet industry expectations for advanced technology nodes? Are they indeed able to reduce manufacturing costs? What are their introduction points into the production environment?

CEA-Leti is working to answer these questions and has initiated collaborative R&D programs to assess and boost the development of these alternative technologies through strategic partnerships. Three programs have been launched with the primary goals of demonstrating that these lithography options can meet industry needs, assessing industrial use of them and proposing to Leti’s IDM partners real turn-key integrated process-flow solutions.

  • IMAGINE: launched in 2009 with MAPPER Lithography, this program is pushing for the insertion of massively parallel direct-write electron-beam technology. Other participants include TSMC, STMicroelectronics, Nissan Chemical, Mentor Graphics, SCREEN, Tokyo Electron and Aselta Nanographics.
  • IDEAL: DSA lithography represents a promising solution for advanced patterning. Leti has worked with Arkema since 2011 on the qualification and demonstration of materials for insertion into industrial production flow. Other partners include ST, Tokyo Electron, SCREEN, Mentor Graphics and CNRS-LCPO.
  • INSPIRE: established in 2015 with the EV Group, this program will focus on the assessment of imprint technology on large-scale patterning.

Directed self assembly: the resolution is in polymer matrix

Since 2010, DSA has steadily attracted attention of R&D laboratories and the IDM industry. The natural high-resolution capability of the block copolymer (sub-10nm) may meet the requirements of future technology nodes. Significant work in this area is underway at R&D consortia such as imec, IBM Research in Albany, N.Y., and Leti, as well as directly in the fab[2,3]. For example, Leti and its partners put in place a full infrastructure to qualify the new material developed by the chemical company Arkema (FIGURE 2). A full 300mm line is operational at Leti using a Tokyo Electron track and a customized SCREEN DUO track able to handle the latest process possibilities. This type of infrastructure is required to validate in fab-like conditions the new materials (PS-PMMA and high chi platforms) and their associated integration flows. Those operating conditions give industry the capability to quickly evaluate the full process-flow performances with all the required classic statistical data for final validation.

Litho Fig 2

Focusing on defectivity Intel showed convincing data at 1def/cm2 on line-and-space structures, confirming the potential of DSA to reach the ITRS target and therefore to be used for manufacturing in the near future (FIGURE 3). As well, Leti results on grapho-epitaxy process are also very encouraging with zero visual-defect process flow for contact/via application measured with low statistical level[4]. Those results are the first positive key trends in the DSA technology. Evaluating the compatibility of DSA with semiconductor process flows is the next important step. The control of the iso-dense configuration focused a lot of attention on the grapho-epitaxy process, in which block copolymer film-filling uniformity is affected by the topography effects of the guide patterns. Leti developed and patented a flow allowing a proper control of CD and CDU in all density configurations. (FIGURE 4) This solution preserves the interest of DSA as it is integrated in the process flow itself and because it does not imply a need for any additional design-rule restriction[4].

Litho Fig 3

Nevertheless, some hurdles remain to be overcome before its final adoption. The control of the surface affinity is one key aspect. It can greatly affect the final defectivity level and impact the complexity of the integration flow (FIGURE 5). Any non-uniform control of the bottom residual polymer thickness in the bottom of the guide cavity may lead to post-etch opening issues and final circuit-yield drop. Moreover, to be fully adopted, DSA technology also must be aligned with the compatible design rule manuals. Insertion in the DRM is essential and it implies adding new specific constraints due to the nature of the block copolymer and to the lithography guide realization. All these R&D efforts must be pushed to value the advantages of DSA technology: the natural high resolution of this solution and its cost effectiveness from reducing multi-exposure strategy. In addition to ensuring DSA’s ability to extend 193nm immersion lithography,it also supports the use of the EUV 0.33NA tool for the development of 7nm nodes and below.

Litho Fig 4

Massively parallel electron-beam writing

Despite recurrent delays in new developments, parallel electron-beam lithography remains an attractive alternative option. The massively parallel writing solutions developed by MAPPER Lithography and IMS Nanofab-rication for wafer and mask writing, respectively, offer good compromises: a significant alliance of resolution and advantageous manufacturing costs. But this technology also benefits from additional advantages, such as writing flexibility and a significant throughput improvement due to the parallel exposure concept that can boost the throughput in the future up to 100 wafers per hour in a cluster-tool configuration. First pre-industrial units are today installed in pilot-line environments, foreshadowing their introduction into production lines in coming years.

MAPPER and Leti’s collaboration is focused on introducing this technology for direct-write application. This joint program started in 2009 around the MAPPER’s pre-alpha tool that validated the key concept of the MAPPER technology in terms of parallel writing and resolution capabilities (FIGURE 6). The partnership entered in a new phase in 2014 with the installation of the first FLX-1200 pre-production platform, (FIGURE 7), operating 1,300 beam lines for a targeted throughput of 1 wph and then scalable to 10 wph by increasing the beam line count up to 13,000.

Litho Fig 5 Litho Fig 6

This FLX-1200, which is being ramped up now, already has shown imaging performances that match its specifications. Full 300mm wafers can be printed in one hour with 32nm half-pitch resolution (FIGURE 8). In the IMAGINE program, Leti and its partners are also working to validate a complete turn-key integrated solution allowing fast and secure wafer processing from design to silicon. Such infrastructure developments around data treatment, materials, process, etch and metrology will be required to speed-up the insertion of the MAPPER technology into future production lines.

Litho Fig 7

Leti and MAPPER will demonstrate the operational capability of the FLX-1200 in its final configuration, including mix-and-match alignment performances. The achievement of this key demonstration milestone is essential to launching this technology. Then, after final ramp-up, the MAPPER platform is expected to be aligned in terms of specifications with 14nm technology (32nm hp). A wide range of potential applications based on its mask-less concept and throughput potential already have been clearly identified: CMOS prototyping and low-volume production, complementary lithography concept for high-end patterning[6], new industry segments (photonics, low-cost circuit functionalization, large field exposure, etc.).

Nano-imprint lithography

Nano-imprint lithography (NIL) stands out from the other conventional lithography processes (photo-lithography, electronic lithography, EUV lithography) because of the fundamental mechanism of creating the final structures. In the case of nano-imprint, the flow of the resist directly shapes the pattern through the stamp cavities, eliminating the need for chemical contrast, as is the case for optical lithography resists. In recent decades, significant efforts have been made to extend the distance between the photomask and the resist-coated wafer to reduce defectivity and enhance resolution. Therefore, for many scientists, NIL technology appeared to be a UFO, since the process is based on the intimate contact between the working stamp and the resist to be embossed.

In the past 20 years, significant progress has been made to make the technology more mature and ready for high-volume manufacturing. Among the several existing NIL technology alternatives, the UV-based imprint, using transparent stamp, is today the standard one. Two well-established options are now available on the market: the full-wafer imprint (the size of the stamp corresponds to the size of the wafer to be printed) and the step-and-flash imprint in which a small stamp (i.e. die size) is stepped, as in optical lithography across the wafer to be processed (FIGURE 9).

Litho Fig 8

If the step-and-flash NIL technology is better suited to address the semiconductor markets (NAND flash memory, DRAM and logic) with its high level-alignment capability and its good control of defectivity density[7], the full-wafer NIL option could quickly become the reference manufacturing option for the emerging and growing markets such as LED and photonics-based devices (FIGURE 10).

Litho Fig 9

However, this wafer-scale imprint solution still lacks quantitative data regarding its technology assessment for high-volume manufacturing. Commercial equipment[8] and resists, the cornerstones of this technology, are already available. But some links in the industrial supply chain (design rules, master manufacturing and repair, in-line defectivity and metrology controls, fully integrated process flows) still must be established and qualified to make this technology more mature.

To accelerate adoption of this technology, Leti and EV Group launched in June 2015 a new collaborative industrial program called INSPIRE, aimed at demonstrating the benefits of this full-wafer NIL technology and spreading its use for applications beyond the traditional semiconductor industry. Much more than a classic industrial partnership, the program is designed to support development of new applications from the feasibility-study stage up to the first manufacturing steps, including the prototyping phase in Leti’s clean room. INSPIRE is also designed to demonstrate the technology’s cost-of-ownership benefits for a wide range of application domains. The final objective of this program is to facilitate the transfer of the developed integrated process solutions to industrial partners. The steps should significantly lower the entry barrier for NIL technology and speed up its use in production lines.

Conclusion

The availability of patterning alternatives in the lithography landscape represents a big opportunity to properly address the coming needs generated by the IoT. Besides conventional optical lithography, they offer industry new and/or complementary advantages: innovation capability and opportunities to better manage cost of ownership. But not only that! The high-resolution potential, the ability to facilitate design-innovation validation, and the complementarity of these alternatives with other patterning solutions also highlight their strengths. The step now is to finalize the evaluation of these technologies with respect to industry standards and establish them as real and credible lithography alternatives.

References

1. A. Schafgans et al, Proc SPIE, Extreme Ultraviolet Lithography VI, Vol. 9422, 2015
2. S. Sayan et al, Proc. SPIE, Advances in Patterning Materials and Processes XXXII, Vol. 9425, 2015
3. H. Tsai et al, ACS nano, vol 8 (5), pp. 5227-5232, 2014
4. R. Tiron et al, Alternative Lithographic Technologies II, Vol. 9423, 2015

The eBeam Initiative, a forum dedicated to the education and promotion of new semiconductor manufacturing approaches based on electron beam (eBeam) technologies, today announced the completion of its fourth annual eBeam Initiative members’ perceptions survey. A record 64 industry luminaries representing 35 different companies from across the semiconductor ecosystem–including chip design, equipment, materials, and manufacturing, as well as photomasks–participated in this year’s survey. The eBeam Initiative also completed its first-ever merchant and captive mask makers’ survey. In related news, ZEISS, a company in lithography optics for semiconductor manufacturing, has joined the eBeam Initiative.

Among the results of the members’ perception survey, respondents expressed increased optimism in the implementation of EUV lithography for semiconductor high-volume manufacturing (HVM) compared to last year’s survey, while at the same time acknowledging that EUV lithography is expected to add greater complexity to photomask manufacturing. In addition, expectations on the use of multi-beam technology for advanced photomask manufacturing continue to remain strong. Results from the eBeam Initiative’s first mask makers survey–which not only provides insight into the challenges and opportunities for photomask manufacturers but also gives mask makers a way to assess their own progress relative to their peers–indicate growing mask complexity across many fronts. The complete results of both surveys will be presented and discussed by an expert panel today during the eBeam Initiative’s annual members meeting at the SPIE Photomask Technology Conference in Monterey, Calif., and are available for download at www.ebeam.org.

Highlights from eBeam Initiative Member Survey

  • 62 percent of respondents predict that multi-beam technology will begin to be used for photomask production by the end of 2016 to address the critical problem of mask write times as the industry moves to smaller geometries.
  • Mask makers appear to be the most optimistic about the availability of multi-beam mask writers, with a near-unanimous 96 percent of mask makers participating in the survey indicating that multi-beam will be used for HVM mask writing by the end of 2018, compared to 65 percent of all equipment suppliers.
  • Among five next-generation lithography (NGL) technologies being considered for advanced semiconductor fabrication, respondents predict EUV as the most likely NGL method to be used in at least one manufacturing step by 2020, with an average confidence rating of 62%.
  • At the same time, 59 percent of respondents predict that EUV will drive the need for complex mask shapes.

Highlights from Mask Makers Survey (data from Q3 2014 through Q2 2015)

  • Mask sets below the 22-nm logic node are exceeding 60 masks for the first time, while mask sets have seen a long-term growth rate of 13 percent since the 250-nm node.
  • Average mask writes times have exceeded the nine-hour mark (9.6 hours) while the longest write time reported was 72 hours.
  • A strong majority (75 percent) of mask makers predict that they will modulate exposure dose on a per-shot basis in 2017.

“eBeam technology is critical to enabling the continuation of Moore’s Law, regardless of which lithography approach is used for semiconductor design and cost scaling,” stated Dr. Markus Waiblinger, senior product manager, strategic business unit Semiconductor Metrology Systems of ZEISS. “As an innovator in the use of eBeam technology for optical and EUV mask inspection, review and repair solutions, ZEISS applauds the eBeam Initiative for educating the semiconductor supply chain about new developments in eBeam technology and for providing a forum for greater collaboration. Efforts like the annual members’ survey and now their first mask makers’ survey play an important role in fulfilling that charter, and we’re pleased to have the opportunity to participate as a new member of the eBeam Initiative.”

“On behalf of the eBeam Initiative, I wish to thank all of our members–including our newest member ZEISS–for their participation in our fourth annual members’ perception survey,” stated Aki Fujimura, CEO of D2S, the managing company sponsor of the eBeam Initiative. “2015 has truly been an exciting year for the Initiative, as members of the eBeam community continue to step forward with new solutions to solve some of the semiconductor and photomask industry’s most pressing manufacturing challenges. Interest and excitement in eBeam technology continues to grow, which is reflected in the record turnout of responses that we received for our annual survey, as well as the strong reception from the global mask community toward our inaugural mask makers’ survey. Feedback from these surveys is invaluable in helping guide our education efforts within the eBeam supply chain, and we look forward to presenting our results for both surveys at the SPIE Photomask Conference later today.”