Category Archives: LEDs

(September 8, 2010) — Researchers of The Hong Kong Polytechnic University (PolyU) have shown that sandwiching a simple layer of silver nanoparticles can significantly improve the performance of organic transistors, which are commonly used in consumer electronics. This is expected to cut down the cost of memory devices such as touchscreens and e-books and improve their performance.

Organic transistor involves the use of organic semiconducting compounds in electronic component. It is a key part of electronic devices like touchscreens. Computer displays enabled by organic transistors are bright with vivid colors. They also provide fast response time and are easy to read in most ambient lighting condition. With the appropriate use of nanotechnology, the performance of organic transistors can be further improved and their size can be made thinner. The novel method developed by PolyU researchers is much more compatible with the low-cost, continuous roll-to-roll fabrication techniques used to make organic electronics.

Follow Small Times on Twitter.com by clicking www.twitter.com/smalltimes. Or join our Facebook group

PolyU researchers have shown that the thickness of the nanoparticle layer changes the memory device performance in a more predictable way, optimizing transistor performance to meet application requirements. Organic transistors made with a 1nm nanoparticle layer have stable memory that lasts for 3 hours, making it suitable for memory buffers. Transistors with a 5nm-thick layer can retain their charge for a much longer time.

The research is led by Dr Paddy Chan Kwok-leung, Assistant Professor of the Department of Mechanical Engineering, and Dr Leung Chi-wah, Assistant Professor of the Department of Applied Physics, with postdoctoral research fellow Dr Sumei Wang as one of the key members. The finding was printed in the latest issue (August 2010) of Applied Physics Letters published by the American Institute of Physics, and has been featured in ScienceDaily. This work will also be presented in the September issue of Chemical Engineering Progress, a publication of the American Institute of Chemical Engineers.

PolyU researchers anticipate a very high potential for the use of organic memory in next-generation memory devices because of its flexibility and relatively low cost.

This research was supported by funding from PolyU and the Research Grants Council.

Read more nanotechnology research reports here.

(September 7, 2010) — The World Fab Forecast released at the end of August indicates a 133% increase in equipment spending for front-end fabs this year and about 18% growth in 2011. Worldwide installed wafer fab capacity (without Discretes) is expected to grow by 7% in 2010 and another 8% in 2011. Fab construction spending will increase by 125% in 2010 and an additional 22% in 2011. The data reveals that for both 2010 and 2011, over 150 fab projects will contribute an estimated $83 billion in spending. The projects tracked include construction projects and equipment spending for high volume, smaller capacity, MEMS, and Discrete, including LED, fabs.

Robust semiconductor equipment spending continues

Most of the current investments in construction assure additional capacity for the future. The World Fab Forecast has identified a total of 54 construction projects underway in 2010 and the result is about $4.5 billion in construction spending. About half of these projects are for LED facilities (mostly in China). In 2011, fewer but larger fabs will carry higher construction costs, about $5.5 billion. 

Follow Solid State Technology on Twitter.com via editors Pete Singer, twitter.com/PetesTweetsPW and Debra Vogler, twitter.com/dvogler_PV_semi. Or join our Facebook group

Spending on equipping fabs will increase by 133% in 2010 to an estimated $34 billion. This is a record growth rate, off of the historic low of 2009, where wafer fab equipment spending struggled to $16 billion, a 10-year low. Compared to 2008 spending, 2010 total equipment spending will be only 27% higher. Compared to 2007, 2010 spending will be 11% lower. The World Fab Forecast report predicts spending in 2011 to increase 18%, bringing total spending to $39B, finally surpassing 2007 spending levels.

SEMI’s World Fab Forecast also provides details of facilities beginning operations in 2010 and 2011. By the end of 2010, about 22 facilities will begin operations. Analyzed by sector, half of these are LED, six are Foundries, three are Analog and two are Logic. No new Memory fabs will begin operation in 2010. In 2011, another 28 facilities are expected to begin operations, including four Memory fabs.

More wafer fab capacity expected

Worldwide installed fab capacity (without Discretes) is expected to grow by 7% by the end of 2010 to 14.4 million 200mm equivalent wafers per month (wpm), and by another 8% in 2011 to 15.8 million wpm. The Memory sector accounts for the largest share of worldwide installed capacity, about 41% in both 2010 and 2011. Foundry capacity follows having grown their market share from 24% in 2009 to 26% in 2011.

SEMI’s World Fab Database reports continue to track individual fab projects very closely. Updates and more information on the reports can be found at www.semi.org/fabs. The SEMI World Fab Forecast report provides high-level summaries and graphs, in-depth analyses of capital expenditure, capacity, technology and products, down to the detail of each fab, and forecasts for the next 18 months by quarter.

SEMI is the global industry association serving the manufacturing supply chains for the microelectronic, display and photovoltaic industries. For more information, visit www.semi.org

For historical data, read Fab spending still a "wild ride" in 2009 by Christian Gregor Dieseldorff, SEMI
SEMI’s World Fab Forecast tracks money spent on frontend semiconductor fabs that are equipping, including R&D and pilot fabs, fab construction projects, and capacity investments per fab. Unlike the SEMI Worldwide Semiconductor Equipment Market Subscription (WWSEMS) data, the World Fab Forecast and its related Fab Database reports track any equipment needed to ramp the fab, upgrade, expand, or change its wafer size regardless if it is new equipment, used equipment, or transferred equipment, while WWSEMS tracks only new equipment.

September 3, 2010 – Researchers at Rice U. say they’ve figured out that new switching memory they built with electrically manipulated 10nm graphite strips doesn’t actually need the graphite — good ol’ reliable silicon oxide will do just fine.

Last year a team led by Rice prof. James Tour showed that electrical current could break and reconnect graphite strips, creating a memory bit.

Now, grad student Jun Yao shows in a Nano Letters paper that the same thing can be achieved with silicon oxide between semiconducting sheets of polycrystalline silicon (as top/bottom electrodes); applying a charge forms a chain of nanosized silicon crystals — as small as 5nm — which can be repeatedly broken and reconnected by varying the voltage. As a proof of concept, he cut a carbon nanotube to localize the switching site, sliced out a thin piece of silicon oxide by focused ion beam, and identified a nanoscale silicon pathway under a transmission electron microscope.

What’s important here? Silicon oxide switches or memory locations require only two terminals, not three (flash memory) because the device doesn’t have to hold a charge. It also can be stacked in 3D arrays, which is the direction memory is going, and would be compatible with conventional CMOS manufacturing technology. And while there are questions about what to do with conventional memory below 20nm, "our technique is perfectly suited for sub-10nm circuits," Tour says in a statement. These SiOx circuits offer similar specs as the original graphite device: high on-off ratios, "excellent" endurance, and <100ns switching. They’re also radiation-resistant (i.e. suitable for defense/aerospace radiation-hardened applications).

From the paper abstract:

Through cross-sectional transmission electron microscopy, we determine that the switching takes place through the voltage-driven formation and modification of silicon (Si) nanocrystals (NCs) embedded in the SiOx matrix, with SiOx itself also serving as the source of the formation of this Si pathway. The small sizes of the Si NCs (d ~ 5nm) suggest that scaling to ultrasmall domains could be feasible. Meanwhile, the switch also shows robust nonvolatile properties, high ON/OFF ratios (>105), fast switching (sub-100ns), and good endurance (104 write-erase cycles).

Austin design firm Privatran is bench-testing a silicon-oxide chip with 1000 memory elements, in work supported by a number of federal groups (NSF, plus the science arms of the Army, Air Force, and Navy). And a Rice spinoff company, NuPGA, is using vertical silicon oxide embedded in vias for rewritable gate array designs.

 

(September 3, 2010 – Marketwire)Palomar Technologies introduced the fully automated 3800 Ultra Flexible Click to EnlargeDie Bonder, created for flexibility, high accuracy and precision.

The 3800 is based on Palomar’s three-generation Model 3500 Die Bonder. The 3.5 um repeatability 3 sigma and 2600 UPH over a 907.1 x 508mm work area enables its user to achieve high accuracy, precision and speed with flexibility in a wide variety of applications. Mutiple options include pulse heat and steady state stages for eutectic die attach applications.

Common applications include eutectic die attach, laser diode packaging and high-power LED packaging. Complex packages, often found in military, optoelectronic and medical devices industries, are well suited for the 3800. The 3800 is designed to eliminate additional bonders in the packaging facility.

Palomar Technologies provides high-precision wire bonders, gold wire bonders, die bonders and automated component placement systems. Find Palomar on the web at www.palomartechnologies.com. Visit Palomar’s blog at www.solutions.palomartechnologies.com.

Follow Advanced Packaging on Twitter.com by clicking www.twitter.com/advpackaging. Or join our Facebook group

(August 23, 2010 – BUSINESS WIRE) — AMD (NYSE: AMD) appointed Donald Newell as vice president and chief technology officer (CTO), Server. A distinguished engineer with more than 20 patents filed, Newell previously served as a senior principle engineer leading the System-on-Chip (SoC) and datacenter networking architecture groups within Intel Labs before joining AMD to lead its server roadmap and platform design programs.

As AMD Server CTO, Newell is responsible for the concept and definition of AMD’s long-term server roadmap based on current conditions, expected demand and long-term server trends. He is leading multiple worldwide teams and working alongside other AMD design and development teams to ensure successful transition of programs from design to market availability. Newell reports to Rick Bergman, senior vice president and general manager, AMD Products Group.

“Don Newell brings a strong combination of leadership skills, engineering and design expertise, and strategic direction,” said Bergman. “We’re fortunate to have Don on board as we prepare for the delivery of the ‘Bulldozer’ core in our AMD Opteron processors, scheduled for launch in 2011.” Intel and AMD have a longstanding rivalry, in business rankings and technology development. Intel is the world’s No. 1 maker of the "brains" of PCs. AMD is No. 2. (Source: Intel, other chip makers suffer on PC sales fears)

During his 16 years with Intel, Newell led development of both SoC and server platform architecture innovations for areas ranging from cloud computing to hand-held devices. Newell also initiated and drove the I/O Acceleration Technologies (IOAT) from initial research to product intercept, developed a detailed architecture for heterogeneous computing and was responsible for delivering the PC industry’s first Digital TV receiver. He led his team to publish seminal papers on areas such as Cache QoS and network protocol processing. Newell has been published in more than 60 peer-reviewed research journals and publications and is a co-author of the IETF RFC2429 that specifies how video is transported over the Internet. Prior to joining Intel, he was a software engineer for first Datanex Software and later Sequent Computers. Newell received a Bachelors of Science from the University of Oregon.

Advanced Micro Devices (NYSE: AMD) is an innovative technology company dedicated to collaborating with customers and technology partners to ignite the next generation of computing and graphics solutions. For more information, visit http://www.amd.com.

Follow Solid State Technology on Twitter.com via editors Pete Singer, twitter.com/PetesTweetsPW and Debra Vogler, twitter.com/dvogler_PV_semi. Or join our Facebook group

Follow Solid State Technology on Twitter.com via editors Pete Singer, twitter.com/PetesTweetsPW and Debra Vogler, twitter.com/dvogler_PV_semi. Or join our Facebook group

(August 17, 2010) — In a podcast interview, Paul Semenza, SVP of Analyst Services at DisplaySearch, explains how a maturing OLED manufacturing capability is contributing to the surge in interest, as is consumer response to products that use OLEDs. One challenge, however, is scaling up vapor deposition, and solutions are being developed. 

Still, he stresses, LCDs aren’t going away anytime soon, and discusses the “battle” between OLEDs and LCDs. The accompanying graph, courtesy of DisplaySearch, indicates continued rapid growth.

OLED revenues in Q1’10 were US$231 million, up 59% Y/Y, and Q2’10 revenues are expected to continue rapid growth. Mobile phones account for 80% of OLED revenues, with the mix moving from small, secondary displays for flip phones to large, main displays for smartphones, enabled by active matrix OLED.

 

  Q109 Q209 Q309 Q409 Q110 Q210
Revenue ($) 145,242 192,310 245,070 243,942 231,204 276,615
Q/Q growth (%) -7 32 27 0 -5 20
Y/Y growth (%) -13 22 84 57 59 44

Listen to the podcast:

Play Now or Download

Read more about LEDS

Return to the Semiconductors center, or go straight to articles on Wafer Processing

(August 17, 2010 – BUSINESS WIRE) — Veeco Instruments Inc. (Nasdaq: VECO) agreed to sell its Metrology business to Bruker Corporation (Nasdaq: BRKR), a leading provider of high-performance scientific instruments and solutions for molecular and materials research, for $229 million in cash. The transaction has been approved by the Board of Directors of both companies and is expected to close in the fourth quarter of 2010, pending regulatory review and subject to customary closing conditions.

The sale will transfer Veeco’s worldwide Metrology business to Bruker, including Veeco’s Atomic Force Microscope (AFM) business in Santa Barbara, CA and its Optical Industrial Metrology (OIM) business in Tucson, AZ, as well as Veeco’s associated global AFM/OIM field sales and support organization. Bruker intends to combine Veeco Metrology with its global Bruker Nano instruments business, which currently sells a broad range of systems and analytical solutions for materials and nanotechnology research. Veeco currently expects cash proceeds from the transaction to be approximately $160 million net of estimated applicable taxes and transaction fees. Additional terms of the transaction were not disclosed. Citigroup Global Markets Inc. acted as exclusive financial advisor to Veeco in connection with the transaction.

John R. Peeler, Veeco’s CEO, commented: "Following the sale of Metrology, Veeco expects to benefit from greater focus on and investment in our LED & Solar and Data Storage Process Equipment businesses. We believe the sale of Metrology will allow us to accelerate our progress developing new products, gaining share, and aligning with key customers in markets with large growth opportunities, including several "clean tech" markets. The sale is also expected to give us additional financial flexibility to pursue acquisitions and expand customer support for our growing Asia business."

Peeler continued, "Veeco Metrology is a great business that is strong, growing and profitable and has many exciting new products. Even so, it lacks meaningful synergies with our Process Equipment businesses in technology, distribution and customers. We believe it will be a better fit as part of a large and successful instrumentation company, such as Bruker, where the focus will be on continued development of innovative scientific instruments. We have great confidence that the Metrology business will continue to grow and prosper as part of Bruker."

Frank H. Laukien, Bruker’s President and CEO, added: "We are excited to add Veeco’s industry-leading scanning probe microscope (SPM) and optical metrology systems to the Bruker product portfolio of high-performance materials research and nanotechnology instruments. We very much look forward to welcoming the customers, management and employees of the Veeco Metrology business to Bruker after the closing of the transaction."

Veeco will account for the Metrology business segment as a "discontinued operation" effective August 15, 2010. Veeco is therefore updating guidance for third quarter 2010 revenue from continuing operations to be in the range of $255-280 million, with GAAP earnings per share between $1.45 and $1.72 and non-GAAP EPS between $1.13 and $1.33. Please see attached GAAP reconciliation table. Without Metrology, Veeco’s updated guidance is that 2010 revenues from continuing operations will be approximately $1 billion, with about 90% from the LED & Solar business segment.

Veeco Instruments Inc. designs, manufactures, markets and services enabling solutions for customers in the HB-LED, solar, data storage, semiconductor, scientific research and industrial markets. http://www.veeco.com/

Read an article from Veeco about AFM, "Detecting failure modes in today’s MEMS" by Noushin Dowlatshahi and Bob Chanapan from Small Times.

Read other articles about analytical equipment for the nano sciences industries here: http://www.electroiq.com/index/nanotech-mems/tools-equipment/analytical-equipment.html

Bruker Corporation (NASDAQ: BRKR) is a provider of high-performance scientific instruments and solutions for molecular and materials research, as well as for industrial and applied analysis. For more information: http://www.bruker.com

August 16, 2010 – SEMI has reorged into three groups to align its focus areas into IC manufacturing, solar photovoltaic (PV), and related/tangential markets including MEMS and LEDs. All three groups will be charged with developing and delivering member services, globally, through SEMI’s regional offices throughout North America, Europe, and Asia.

The organization’s semiconductor IC business unit will be led by Jonathan Davis, formerly president of SEMI Americas, who will have global profit/loss responsibility for all SEMICON expos, market research, and statistics programs, as well SEMI’s standards efforts. Karen Savala, formerly VP of member services, will take the helm at SEMI Americas, including public advocacy efforts.

Dan Martin will continue to lead SEMI’s PV Group, which is being recognized as a dedicated SEMI business unit. Bettina Weiss, senior director of the PV Group, is promoted to executive director with additional global responsibilities.

Directing SEMI’s activities within its "emerging and adjacent markets" unit is Tom Morrow — which he will take on in addition to his role as SEMI’s chief marketing officer and VP of global expositions.

Each of these groups have process technologies in common and a need for supply chain collaboration, explained Stanley Myers, president and CEO of SEMI, in a statement. But splitting them up will help make SEMI more responsive and offer specialized attention. "These changes are intended to more effectively and efficiently address the increasing complexity and diversity of member needs serving the IC, PV, LED, MEMS, and other markets," he stated.

by Michael A. Fury, Techcet Group

August 16, 2010 – The 3rd and final half-day of the 15th Annual Clarkson CAMP CMP Symposium progressed with a sustaining attendance that belies the significance of the content value of this meeting. It was gratifying to see a quite respectable audience size even for the final talk.

Click to EnlargeLieve Teugels of IMEC woke us up with horrifying pictures of "fangs" — those nasty copper chemical mechanical planarization (CMP) galvanic corrosion artifacts at the copper-barrier interface. Electrochemical studies were conducted with BTA and another commercial surfactant in development, and Ta barrier with other barrier metals to come.

Srini Raghavan of the U. of Arizona showed how to use sonoluminescence to study the role of dissolved gases in megasonic cleaning, with an eye toward optimizing PCMP and other wafer cleaning. Dissolved CO2 may function as a free radical scavenger that extends the lifetime of ozone in water.

Len Borucki described a joint effort between Araca joint with Entrepix: a slurry injector that rests on the pad, serving a dual purpose of distributing fresh slurry immediately ahead of the wafer carrier and forming a bow wave to divert the used slurry coming around on the platen to the platen edge. Slurry flow was reduced 36% while maintaining removal rate. Under optimized conditions, there is a minimal slurry bow wave at the wafer carrier as slurry flows in a thin film, reducing slurry waste.

Deepak Mahulikar of Planar Solutions talked about the requirements for ultrapure colloidal silica for Cu slurry. Chemical contaminants in the silica have been implicated in corrosion, scratching & fangs in Cu CMP. Planar is producing a colloidal silica using fumed silica as a source material.

James Kelly of IBM Research discussed the correlation of Cu plating levelers with CMP planarization results. Rather than optimizing the leveler to reduce the load on CMP, the motivation for the work was to simplify to copper plating bath in order to rely more heavily on CMP for excess Cu removal. Even though the post-CMP topography showed <10nm difference between leveler and no leveler, the difference in electrical serpentine shorts was almost 100×. Yield results could be made comparable by adding a 20sec touch-up polish to the no-leveler wafers. The conclusion, however, is that if you want to maintain a low Cu plating overburden, the leveler should not be eliminated.

SEE ALSO:
Day 2: Porosity on demand, CMP whack-a-mole, end-of-line acronym soup
Day 1: CMP’s FEOL future, "dark art" defect work, mysterious Cu dendrites

Takeshi Nogami, representing IBM’s Interconnect Group at Albany Nanotech, presented work on CVD Co as a Cu barrier and the resulting CMP implications. Co is an effective barrier for Cu, but not for O2 and H2O. To eliminate Cu oxidation, a PVD TaN/CVD Co/PVD Cu seed scheme was evaluated. Corrosion fangs post-CMP were worse with TaN/Co than with TaN/Ta. Co is not ruled out for 22nm, but additional work is required.

David Merricks from Ferro showed work on sapphire polishing with alumina abrasive for HB-LED applications. Samsung, TSMC, UMC, Micron, and others are entering the LED foundry market to utilize 150mm and 200mm excess capacity. Sapphire single-crystal wafers can be grown and processed like Si up to 200mm. The Ferro alumina slurry replaces a diamond slurry, and delivers ~8μm/hr removal and a final 0.2nm Ra. The alumina process is true chemical-mechanical, whereas diamond is all-mechanical.

The use of combinatorial methods for developing PCMP cleaning chemistries was presented by Steve Bilodeau, reporting on joint work involving ATMI, Intermolecular and IBM (Albany). Complex chemical processes are often highly non-linear, making multivariant techniques not only more effective but essential. Key variables included pH, solvating agent, passivator, corrosion inhibitor, and surfactant at two levels each. Measured responses included data scatter, passivation layer thickness, Cu loss and slurry cleaning. Minimum corrosion inhibitor provided the best cleaning, while pH could be modulated to minimize the passivation layer thickness.

In addition to the many fine papers presented at the Clarkson CAMP CMP Symposium, there were 14 poster papers presented by the students and faculty at Clarkson. The poster titles & professor are provided here; for further information, contact the professor at Clarkson directly.

  1. Effect of polishing pad on tunable removal rates of polysilicon, SiO2 and SiNx films (Babu).
  2. CMP of black diamond films (Babu).
  3. Role of ionic strength, hydroxyl ions & radicals, & abrasives on Ge CMP in H2O2-based slurries (Babu).
  4. A high removal rate Cu slurry for TSV applications (Li, with BASF).
  5. Particle agglomeration in the CMP process (Li).
  6. Development of an amine-free Cu PCMP cleaner (Li).
  7. Electrochemical impedance studies of surface reactions for chemically enhanced CMP of Ta using oxalic acid as a complexing agent (Roy & Babu).
  8. Chemical mechanisms of CMP of Cu & Ta in tartaric acid-based slurries investigated with electrochemical techniques (Roy & Babu).
  9. Study of mechanical properties of polymer pads with AFM & nanoindentation techniques (Sokolov).
  10. Studies on preparation of polymer core — ceria shell particles for CMP evaluation (Partch).
  11. Effects of electrostatic & capillary forces on particle detachment with surface deformation in turbulent flows (Ahmadi).
  12. Particle adhesion & removal mechanisms by hydrodynamic force in CMP cleaning processes (Ahmadi & Ferro).
  13. Electrochemical methods for testing Ta CMP slurries (Suni & Li).
  14. Fundamental studies of Cu ECMP electrolytes (Suni & Li, with Air Liquide).

My attendance at this meeting was motivated by the fact that it was the 15th anniversary of this symposium. Prof. Babu thought it would be nice for me to give a dinner talk on Tuesday evening about the early days of CMP, as I am the individual held most responsible for instigating the CMP programs at Clarkson. I was honored to do so — and I express my thanks to Prof. Babu and his colleagues at Clarkson for developing and sustaining a program that has grown far beyond my expectations.

I also decided to have a little fun with my time on the podium in the relaxed environment at Lake Placid, NY. The lyrics to my ode to chip development can be found online, but interested performers will have to supply their own karaoke music and stage support.


Michael A. Fury, Ph.D, is senior technology analyst at Techcet Group, LLC, P.O. Box 29, Del Mar, CA 92014; e-mail [email protected].

by Michael A. Fury, Techcet Group

August 13, 2010 – Day 2 of the 15th Annual Clarkson CAMP CMP Symposium was led by Manabu Tsujimura, corporate CTO at Ebara, who spoke on surviving the Ice age as we transition from 45nm to 20nm. While some are talking about going back to aluminum interconnects when copper reaches its electron scattering limits, Tsujimura is content to leave it marked "unknown," though he cites tungsten as one additional option. His overall message is that equipment manufacturers need their own paradigm shift for process tools if they intend to survive the upcoming node transitions.

Hiroyuki Tano from JSR Research presented some characterization work on JSR pad polymer compositions, which contain water soluble poromers that create pad "porosity on demand" as they are exposed by pad conditioning. Effective surface hardness is engineered to deliver an acceptable trade-off between planarity and defects.

Click to EnlargeFred Sun of Cabot Microelectronics spoke about system-level optimization in CMP to concurrently maximize performance and CoO. Specific interactions between pad and conditioner were quantified against performance results, confirming that the industry’s current process is well into the regime in which 2nd– and 3rd-order interactions are significant. He says the demands of advanced CMP system optimization are like solving Rubik’s Cube — whereas addressing single components is more like Whack-A-Mole.

Keiichi Kimura from the Kyushu Institute of Technology described their early attempts to analyze the conditioned pad surface and material removal mechanism using FFT topography and spatial frequency analysis. Differences in spatial wavelength were observed as a function of conditioner abrasive design pattern and diamond grit diameter. This is believed to be related to slurry flow stability between the wafer and pad.

Taewook Hwang of Saint-Gobain Abrasives talked about controlling the conditioner cut rate characteristics as a function of diamond shape. A systematic correlation of pad texture with diamond shape was produced for several different kinds of pads. While IC1000 is the standard pad for such studies historically, the Cabot D100 has played a prominent role in this study and several others in this symposium.

The evolution of CMP process control led into an introduction of Applied Materials’ latest techniques designed specifically for Cu processing. Jimin Zhang described how incoming film thickness and uniformity measurements are used to compute a set of custom process conditions for each wafer. However, real time process control is still required to consistently achieve ever-tightening specs.

SEE ALSO:
Day 1:CMP’s FEOL future, "dark art" defect work, mysterious Cu dendrites

Bastian Noller of BASF introduced their latest approaches for dealing with CMP for through-silicon vias (TSV), as well as a new (to me) acronym: BFEOL, which means "before FEOL." (Someone needs to come up with a "final BEOL" process to complete the set — FEOL, BEOL, BFEOL, FBEOL — but I digress.) Their optimization of a TSV Cu slurry hinges on a dual crosslinking inhibitor and frangible polymer abrasive particles.

Samsung’s Jongwon Lee described the use of a sacrificial polymer layer to boost planarization efficiency of SiO2 polishing. Photoresist is routinely used experimentally, but is too expensive to use in volume production. Their CFSP (CMP-friendly sacrificial polymer) is essentially a hardened photoresist resin without the expensive photo-active compounds.

Haedo Jeong from Pusan National U. used bare Si wafers to analyze changes in friction in process phenomena associated with CMP. This early work focused on pad conditioning and break-in, and may prove to be a useful framework for future study.

Andreas Klipp of BASF walked us through the systematic approach that was used to develop their Planapur R-P0D cleaning product for Cu PCMP. This work highlights the amount and variety of experimental data that is required to commercialize products for volume chip production. Complete removal of BTA and restoration of low-k dielectric constant are among the key design criteria that were successfully met.

Chintan Patel from Entegris spoke about their modified charge, ultra-clean PVA brushes. The essential trick is formulating the brush materials with a negative zeta potential to minimize the accumulation of particles in the brush while still effectively removing them from the wafer surface. Modified features at both ends of the brush are shown to improve the wafer edge cleaning.


Michael A. Fury, Ph.D, is senior technology analyst at Techcet Group, LLC, P.O. Box 29, Del Mar, CA 92014; e-mail [email protected].