Tag Archives: semiconductor

Nowhere Near Room Temp Superconductors

On-chip metal interconnects limit IC speed in many advanced design today, and with signal delay proportional to the product of the resistance (R) of wires and the capacitance (C) of dielectric insulation, wires with R lower than that of copper (Cu) metal would significantly improve IC performance. We know of superconductors—materials with zero resistance to electrical current flow—but only at “critical temperature” (Tc) well below 77°K, and so there has been an ongoing quest by scientists to find a material with Tc above room temperature of 298°K.

Sadly, after 4 years and nearly 1000 materials tested, a team of 6 Japanese research groups led by Hideo Hosono from the Tokyo Institute of Technology found no room temperature superconductors. They did find 100 previously unknown superconductors with Tc <56°K, and they published crystal structures and phase diagrams of all materials studied to help other researchers avoid now known dead-ends (DOI: 10.1088/1468-6996/16/3/033503).

Other researchers continue to explore the possibilities of using one-dimensional (1D) carbon-based materials such as carbon-nano-tubes (CNT) or graphene as on-chip conductors. So far, there are extreme difficulties in controlling the growth of such 1D structures within interconnect patterns, and additional challenges with forming ohmic contacts between CNT and Cu lines across billions of connections in a modern IC. More science is seemingly needed to find new paths before the engineers can explore those paths to find better solutions. Meanwhile…for the next few years at least…expect Cu metal to be the continued choice for nearly all multi-level metal interconnects on chip.

—E.K.

Cross-point ReRAM Integration Claimed by Intel/Micron

The Intel/Micron joint-venture now claims to have successfully integrated a Resistive-RAM (ReRAM) made with an unannounced material in a cross-point architecture, switching using an undisclosed mechanism. Pilot production wafers are supposed to be moving through the Lehi fab, and samples to customers are promised by end of this year.
HP Labs announced great results in 2010 on prototype ReRAM using titania without the need for a forming step, and then licensed the technology to Hynix with plans to bring a cross-point ReRAM to market by 2013. SanDisk/Toshiba have been working on ReRAM as an eventual replacement for NAND Flash for many years, with though a bi-layer 32Gb cross-point ReRAM was shown at ISSCC in 2013 they have so far not announced production.
Let us hope that the folks in Lehi have succeeded where HP/Hynix and SanDisk/Toshiba among others have so far failed in bringing a cross-point ReRAM to market…so this may be a “breakthrough” but it’s by no means “revolutionary.” Until the Intel/Micron legal teams decide that they can disclose what material is changing resistance and by what mechanism (including whether an electrical “forming” step is needed), the best we can do is speculate as to even how much of a breakthrough this represents.
—E.K.

CMP Slurry Trade-offs in R&D

As covered at SemiMD.com, the CMP Users Group (of the Northern California Chapter of The American Vacuum Society) recently held a meeting in Albany, New York in collaboration with CNSE, SUNY Polytechnic Institute, and SEMATECH. Among the presentations were deep dives into the inherent challenges of CMP slurry R&D.
Daniel Dickmann of Ferro Corporation discussed trade-offs in designing CMP slurries in his presentation, “Advances in Ceria Slurries to Address Challenges in Fabricating Next Generation Devices.” Adding H2O2 to ceria slurry dramatically alters the zeta-potential of the particles and thereby alters the removal rates and selectivities. For CMP of Shallow Trench Isolation (STI) structures, adding H2O2 to the slurry allows for lowering of the particle concentration from 4% to <2% while maintaining the same removal rate. Reducing the average ceria particle size from 130nm to 70nm results in a reduction in scratch defects while maintaining the same removal rate by tuning the chemistry, but the company has not yet found chemistries that allow for reasonable removal rates with 40nm diameter particles. The ceria morphology is another variable that must be controlled according to Dickmann, “It can seem counter-intuitive, but we’ve seen that non-spherical particles can demonstrate superior removal-rates and defectivities compared to more perfect spheres.”
Selectivity is one of the most critical and difficult aspects of the CMP process, and arguably the key distinction between CMP and mere polishing. The more similarity between the two or more exposed materials, the more difficult to design high selectivity in a slurry. Generally, dielectric:dielectric selectivity is difficult, and how to develop a slurry that is highly selective to nitride (Si3N4) instead of TEOS-oxide (PECVD SiO2 using tetra-ethyl-ortho-silicate precursor) was discussed by Takeda-san of Fujimi Corporation. In general, dielectric CMP is dominated by mechanical forces, so the slurry chemistry must be tuned to achieve selectivity. Choosing <5 pH for the slurry allows for reducing the oxide removal rate while maintaining the rate of nitride removal. Legacy nitride slurries have acceptable selectivities but unacceptable edge-over-erosion (EOE) – the localized over-planarization often seen near pattern edges. Reducing the particle size reduces the mechanical force across the surface such that chemical forces dominate the removal even more, while EOE can be reduced because negatively charged particles are attracted to the positively charged nitride surface resulting in local accumulation.
—E.K.